AI Article Synopsis

  • The compound [Co(C(44)H(24)Cl(4)N(4)){(C(4)H(9))(3)P}(2)]ClO(4) features a cobalt(III) center with a slightly distorted octahedral geometry.
  • The cobalt is bonded to four nitrogen atoms from a tetra-pyrrolic ring and two phosphine ligands, influencing its overall structure.
  • The crystal structure is stabilized through multiple interactions, including C-H⋯Cl, C-H⋯O, C-H⋯N, and C-H⋯π interactions.

Article Abstract

In the mol-ecule of the title compound, [Co(C(44)H(24)Cl(4)N(4)){(C(4)H(9))(3)P}(2)]ClO(4), the Co(III) centre has a slightly distorted octa-hedral geometry and is coordinated by four N atoms of the tetra-pyrrolic ring in the equatorial positions and two phosphine ligands in the axial positions. The dihedral angles between meso-substituted chloro-phenyl rings and the basic tetra-pyrrolic ring are 82.66 (9), 82.16 (7), 83.97 (11) and 76.87 (8)°. In one of the phosphine ligands, the two terminal methyl groups are disordered over two positions with refined site-occupancy ratios of 0.70 (7):0.30 (7) and 0.66 (2):0.34 (2). In the crystal structure, mol-ecules are linked together along the a axis by inter-molecular C-H⋯Cl inter-actions. The crystal structure is further stabilized by intra-molecular C-H⋯O and C-H⋯N inter-actions and inter-molecular C-H⋯O and C-H⋯π inter-actions.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969721PMC
http://dx.doi.org/10.1107/S1600536809019163DOI Listing

Publication Analysis

Top Keywords

tetra-pyrrolic ring
8
phosphine ligands
8
crystal structure
8
[5101520-tetra-kis4-chloro-phen-ylporphyrinato]bis-tributyl-phosphinecobaltiii perchlorate
4
perchlorate mol-ecule
4
mol-ecule title
4
title compound
4
compound [coc44h24cl4n4{c4h93p}2]clo4
4
[coc44h24cl4n4{c4h93p}2]clo4 coiii
4
coiii centre
4

Similar Publications

Article Synopsis
  • The compound [Co(C(44)H(24)Cl(4)N(4)){(C(4)H(9))(3)P}(2)]ClO(4) features a cobalt(III) center with a slightly distorted octahedral geometry.
  • The cobalt is bonded to four nitrogen atoms from a tetra-pyrrolic ring and two phosphine ligands, influencing its overall structure.
  • The crystal structure is stabilized through multiple interactions, including C-H⋯Cl, C-H⋯O, C-H⋯N, and C-H⋯π interactions.
View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!