AI Article Synopsis
- The compound is a copper complex with the formula [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, obtained from a specific molar mixture involving copper(II) tetra-fluoridoborate and di-2-pyridyl ketone.
- The complex has a centrosymmetric structure, with its cation similar to known structures but shows a distortion in its geometry, where the Cu-O bonds deviate by 25 degrees from the ideal octahedral shape.
- Additionally, the BF(4)(-) anion displays disorder in its fluorine atoms, occurring in two different configurations with a noted statistical ratio.
Article Abstract
The title complex, [Cu(C(11)H(10)N(2)O(2))(2)](BF(4))(2)·2H(2)O, was isolated as a dihydrate from a 1:2 molar mixture of copper(II) tetra-fluoridoborate hexa-hydrate with di-2-pyridyl ketone in aqueous solution. The centrosymmetric complex cation is structurally similar to that found in previously reported salts and exhibits Cu-O bonds deviating by 25 degrees from an octa-hedral geometry by the so-called 'off-axis angle' distortion. The BF(4) (-) anion exhibits a two site disorder of the fluorine atoms [ratio 0.210 (8):0.790 (8)].
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969716 | PMC |
| http://dx.doi.org/10.1107/S1600536809016973 | DOI Listing |
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