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(E)-Methyl N'-(2-hydr-oxy-3-methoxy-benzyl-idene)hydrazinecarboxyl-ate. | LitMetric

AI Article Synopsis

  • The compound C(10)H(12)N(2)O(4) features a trans configuration for its C=N double bond and has its non-hydrogen atoms nearly coplanar.
  • The molecule exhibits an intramolecular interaction between an O-H and an N atom.
  • In its crystal structure, molecules form a two-dimensional network through various hydrogen bonds and a C-H⋯π interaction, reinforcing their stability.

Article Abstract

The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol-ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra-molecular O-H⋯N inter-action is observed. In the crystal structure, the mol-ecules are linked into a two-dimensional network parallel to the ac plane by N-H⋯O hydrogen bonds involving the meth-oxy O atom and by two C-H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C-H⋯π inter-action is observed.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969457PMC
http://dx.doi.org/10.1107/S1600536809021631DOI Listing

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