The title compound, C(13)H(15)NP(+)·Cl(-), was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyl-imino-phosphine. The dihedral angle between the phenyl rings in the cation is 61.5 (3)°. In the crystal structure, inter-molecular N-H⋯Cl hydrogen bonds links the two components, forming a centrosymmetric 2 + 2 aggregate.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969268 | PMC |
| http://dx.doi.org/10.1107/S1600536809020698 | DOI Listing |
Publication Analysis
Top Keywords
methyldiphenyl-phospho-ranylidene-ammonium chloride
4
chloride title
4
title compound
4
compound c13h15np+·cl-
4
c13h15np+·cl- hydrolysis
4
hydrolysis n-trimethysilyl
4
n-trimethysilyl derivative
4
derivative methydiphenyl-imino-phosphine
4
methydiphenyl-imino-phosphine dihedral
4
dihedral angle
4
Similar Publications
(Methyldiphenyl-phospho-ranylidene)-ammonium chloride.
Acta Crystallogr Sect E Struct Rep Online
June 2009
The title compound, C(13)H(15)NP(+)·Cl(-), was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyl-imino-phosphine. The dihedral angle between the phenyl rings in the cation is 61.5 (3)°.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!