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Bis(3,5-dimethyl-pyridine-κN)bis-(tri-tert-butoxy-silanethiol-ato-κS)chromium(II) toluene solvate. | LitMetric

Bis(3,5-dimethyl-pyridine-κN)bis-(tri-tert-butoxy-silanethiol-ato-κS)chromium(II) toluene solvate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Technical University of Gdańsk, 11/12 G. Narutowicz St., 80233-PL Gdańsk, Poland.

Published: June 2009

AI Article Synopsis

Article Abstract

In the title chromium silanethiol-ate, [Cr(C(12)H(27)O(3)SSi)(2)(C(7)H(9)N)(2)]·C(7)H(8), the Cr(II) atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear mol-ecule lies on a twofold axis that passes through the pyridine N atoms. The toluene solvent mol-ecule is equally disordered about a twofold axis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969383PMC
http://dx.doi.org/10.1107/S1600536809021680DOI Listing

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