In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4'-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octa-hedral coordination geometry involving four water mol-ecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxyl-ate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular network.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969229 | PMC |
| http://dx.doi.org/10.1107/S1600536809019412 | DOI Listing |
Publication Analysis
Top Keywords
twofold rotation
8
rotation axis
8
catena-poly[[[tetra-aqua-zincii]-μ-44'-bipyridine-κnn'] benzene-14-di-carboxyl-ate]
4
benzene-14-di-carboxyl-ate] title
4
title compound
4
compound {[znc10h8n2h2o4]c8h4o4}n
4
{[znc10h8n2h2o4]c8h4o4}n znii
4
znii atoms
4
atoms lying
4
lying twofold
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!