The title compound, C(14)H(11)Cl(2)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. There are two mol-ecules in the asymmetric unit. Head-to-tail π-π inter-actions [centroid-to-centroid distances of 3.682 (2), 3.708 (2), 3.904 (2) and 3.910 (2) Å] between adjacent mol-ecules produce two symmetry-independent infinite chains running along the b axis.
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http://dx.doi.org/10.1107/S1600536809009684 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
October 2020
Department of Computer and Electronic Engineering Technology, Sana'a Community, College, Sana'a, Yemen.
The title compound, CHINO, was synthesized by condensation of 2-hy-droxy-3-methyl-benzaldehyde and 2-iodo-aniline, and crystallizes in the ortho-rhom-bic space group 222. The 2-iodo-phenyl and benzene rings are twisted with respect to each other, making a dihedral angle of 31.38 (2)°.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
February 2020
Department of Chemistry, Taras Shecchenko National University of Kyiv, 64, Vladimirska Str., Kiev 01601, Ukraine.
In the crystal structure of the title compound, CHClNO, the mol-ecules are linked through C-H⋯O hydrogen bonds and C-H⋯π inter-actions, forming chains parallel to the [010] direction. π-π inter-actions and intra-molecular hydrogen bonds are also observed. The mol-ecular geometry of the title compound in the ground state has been calculated using density functional theory at the B3LYP level with the 6-311++G(2,2) basis set.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
August 2010
School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, People's Republic of China.
The title compound, C(14)H(12)ClNO, a Schiff base derived from 3-methyl-salicyl-aldehyde, crystallizes in the phenol-imine tautomeric form with an E conformation for the imine functionality. The mol-ecule is not planar, the dihedral angle between the aromatic rings being 36.38 (5)°.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
June 2010
The title compound, C(14)H(12)INO, adopts the phenol-imine tautomeric form. The dihedral angle between the aromatic rings is 20.6 (3)°.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
March 2009
The title compound, C(14)H(11)Cl(2)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. There are two mol-ecules in the asymmetric unit. Head-to-tail π-π inter-actions [centroid-to-centroid distances of 3.
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