(SP-4-4)-[Hydrogen N-({2-[(2S)-1-benzyl-pyrrolidine-2-carboxamido]phen-yl}(phen-yl)methyl-ene)-l-glutamato(2-)]nickel(II).

Acta Crystallogr Sect E Struct Rep Online

College of Life Science and Pharmaceutical Engineering, Nanjing University of Technology, Xinmofan Road No. 5 Nanjing, Nanjing 210009, People's Republic of China.

Published: March 2009

In the mol-ecule of the title complex, [Ni(C(30)H(29)N(3)O(5))], the Ni atom is coordinated in a distorted square-planar geometry by three N and one O atoms. The aromatic rings are oriented at dihedral angles of 29.01 (3), 79.73 (3) and 83.37 (3)°. The remaining rings adopt envelope conformations with the C and N atoms at the flap positions. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along the b axis. There is also a weak C-H⋯π inter-action.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968851PMC
http://dx.doi.org/10.1107/S1600536809010861DOI Listing

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(SP-4-4)-[Hydrogen N-({2-[(2S)-1-benzyl-pyrrolidine-2-carboxamido]phen-yl}(phen-yl)methyl-ene)-l-glutamato(2-)]nickel(II).

Acta Crystallogr Sect E Struct Rep Online

March 2009

College of Life Science and Pharmaceutical Engineering, Nanjing University of Technology, Xinmofan Road No. 5 Nanjing, Nanjing 210009, People's Republic of China.

In the mol-ecule of the title complex, [Ni(C(30)H(29)N(3)O(5))], the Ni atom is coordinated in a distorted square-planar geometry by three N and one O atoms. The aromatic rings are oriented at dihedral angles of 29.01 (3), 79.

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