The water-coordinated metal atom in the title compound, [Cu(C(7)H(4)NO(4))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], lies on a center of inversion in an all-trans octa-hedral environment with slight distortions. The mol-ecule inter-acts with adjacent mol-ecules through O-H⋯O and N-H⋯O hydrogen bonds, forming a layered network parallel to (010).
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http://dx.doi.org/10.1107/S1600536809007995 | DOI Listing |
J Phys Chem A
July 2024
Department of Chemistry and Biochemistry, The University of Alabama, Shelby Hall, Tuscaloosa, Alabama 35487-0336, United States.
Int J Mol Sci
April 2024
Division of Materials Chemistry, Ruđer Bošković Institute, Bijenička 54, 10000 Zagreb, Croatia.
This study aimed to synthesize molybdenum complexes coordinated with an aroyl hydrazone-type ligand (HL), which was generated through the condensation of 2-hydroxy-5-nitrobenzaldehyde with benzhydrazide. The synthesis yielded two types of mononuclear complexes, specifically [MoO(L)(MeOH)] and [MoO(L)(HO)], as well as a bipyridine-bridged dinuclear complex, [(MoO(L))(4,4'-bpy)]. Those entities were thoroughly characterized using a suite of analytical techniques, including attenuated total reflectance infrared spectroscopy (IR-ATR), elemental analysis (EA), thermogravimetric analysis (TGA), and single-crystal X-ray diffraction (SCXRD).
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2024
CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Prussian blue analogues receive tremendous attention owing to their spacious three-dimensional skeleton, high theoretical specific capacity, facile synthesis procedure, and high cost-effectiveness as among the most promising candidates for cathode materials in sodium-ion batteries (SIBs). Nonetheless, the practical specific capacity, especially under high current, is particularly frail due to the sluggish ion diffusion. In this study, the strategy of Ni substitution and formation of water-coordinated Fe is applied to lower the crystal field energy and elevate the active low-spin (LS) Fe content, which leads to a capacitive sodium storage mechanism, resulting in a substantial specific capacity under high current density.
View Article and Find Full Text PDFJ Am Chem Soc
April 2024
Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi 464-8602, Japan.
Many unique adsorption properties of metal-organic frameworks (MOFs) have been revealed by diffraction crystallography, visualizing their vacant and guest-loaded crystal structures at the molecular scale. However, it has been challenging to see the spatial distribution of the adsorption behaviors throughout a single MOF particle in a transient equilibrium state. Here, we report three-dimensional (3D) visualization of molecular adsorption behaviors in a single crystalline particle of a MOF by X-ray absorption fine structure spectroscopy combined with computed tomography for the first time.
View Article and Find Full Text PDFInorg Chem
January 2024
Max Planck Institute for Solid State Research, Heisenberg strasse 1, D-70569 Stuttgart, Germany.
Two pseudopolymorphic 1D coordination polymers of the formulas [Cd(3,3'-pytz)(CHOH)(ClO)] () and [Cd(3,3'-pytz)(CHCN)(ClO)] () have been prepared using the electron-deficient 3,6-bis(pyridin-3-yl)-1,2,4,5-tetrazine (3,3'-pytz) ligand and cadmium perchlorate in the chloroform/methanol and chloroform/acetonitrile solvent system, respectively. It was observed that compounds and experienced one-step (CP → CP) single-crystal-to-powder structural transformation to the pure water-coordinated compound [Cd(3,3'-pytz)(HO)(ClO)] () by absorbing water vapor from air (solid-gas phase transformation). Interestingly, compounds , , and undergo a different transformation path and show an in situ unique three-step (CP → CP → Ligand → CP) single-crystal-to-single-crystal (SCSC) structural transformation process through soaking in deionized water (solid-liquid phase transformation).
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