Bis(benzoyl-acetonato)bis-(1,3-di-4-pyridyl-propane)manganese(II).

Acta Crystallogr Sect E Struct Rep Online

Published: March 2009

In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa-hedral coordination environment. Weak π-π stacking inter-actions, with centroid-centroid distances of 3.862 (2) and 3.887 (5) Å, and significant C-H⋯π inter-actions help to stabilize the crystal structure. The atoms of the unique terminal 4-pyridine-propane group are disordered over two sites, the ratio of refined occpancies being 0.712 (7):0.288 (7).

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969015PMC
http://dx.doi.org/10.1107/S1600536809009891DOI Listing

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