Poly[(μ-4,4'-bipyridine)(μ-naphthalene-1,4-dicarboxyl-ato)manganese(II)].

Acta Crystallogr Sect E Struct Rep Online

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24098 Kiel, Germany.

Published: March 2009

In the crystal structure of the title compound, [Mn(C(12)H(6)O(4))(C(10)H(8)N(2))](n), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxyl-ate anions and two N atoms of two symmetry-related 4,4'-bipyridine ligands within a strongly distorted octa-hedra. Two of the O atoms originate from one naphthalene-1,4-dicarboxyl-ate anion, whereas the remaining two O atoms derive from two symmetry-equivalent naphthalene-1,4-dicarboxyl-ate anions. Two Mn atoms are connected via the anions into dimers, which are further linked by the anions and the N-donor ligands into a three-dimensional coordination network.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968939PMC
http://dx.doi.org/10.1107/S1600536809009301DOI Listing

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