The title compound, {[Tm(C(7)H(3)NO(4))(C(7)H(4)NO(4))(H(2)O)(2)]·2H(2)O}(n), is isotypic with the analogous Tb(III) compound [Li et al. (2009 ▶). Acta Cryst. E65, m410]. All interatomic distances and angles and the hydrogen-bond geometries are very similar for the two structures. The refined Flack parameter of 0.49 (2) suggests inversion twinning.
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Synthesis, structure and photoluminescence properties of heterometallic-based coordination polymers of trimesic acid.
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Acta Crystallogr E Crystallogr Commun
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Acta Crystallogr E Crystallogr Commun
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School of Chemistry, University of St Andrews, KY16 9ST, Scotland, United Kingdom.
Single crystals of three novel transition-metal oxalates, dirubidium di-aqua-dioxalatocobalt(II) dihydrate or dirubidium cobalt(II) bis-(oxalate) tetra-hydrate, Rb[Co(CO)(HO)]·2HO, (I), -poly[dirubidium [[di-chlorido-cobalt(II)]-μ-oxalato]] or dirubidium cobalt(II) dichloride oxalate, {Rb[CoCl(CO)]} , (II), and poly[dipotassium [tri-μ-oxalato-copper(II)dilithium] dihydrate] or dipotassium dilithium copper(II) tris-(oxalate) dihydrate, {K[LiCu(CO)]·2HO} , (III), have been grown under hydro-thermal conditions and their crystal structures determined using single-crystal X-ray diffraction. The structure of (I) exhibits isolated octa-hedral [Co(CO)(HO)] units, whereas (II) consists of chains of Co ions bridged by bidentate oxalato ligands and (III) displays a novel tri-periodic network of Li and Cu ions linked by oxalato bridging ligands.
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Acta Crystallogr E Crystallogr Commun
October 2022
Department of Chemistry, Faculty of Science and Technology, Thammasat University, Klong Luang, Pathum Thani 12121, Thailand.
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Acta Crystallogr E Crystallogr Commun
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L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prospekt Nauki 31, Kyiv, 03028, Ukraine.
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