1,3-Bis[(6-methyl-2-pyrid-yl)meth-yl]imidazolium bromide.

Acta Crystallogr Sect E Struct Rep Online

Published: February 2009

The title compound, C(17)H(19)N(4) (+)·Br(-), is built up from 1,3-bis-[(6-methyl-2-pyridin-yl)meth-yl]imidazolium cations and bromide anions. Each of two 6-methyl-2-pyridyl rings is rotated out of the imidazole plane, making dihedral angles of 79.90 (9) and 86.40 (9)°. The packing is consolidated by aromatic π-π inter-actions between the pyridine rings of neighbouring mol-ecules [centroid-centroid distance = 3.554 (2) Å] and by weak C-H⋯N and C-H⋯Br hydrogen bonds.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968481PMC
http://dx.doi.org/10.1107/S1600536809006710DOI Listing

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