Nitratotris(triphenyl-phosphine)copper(I) methanol solvate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of the Free State, Bloemfontein 9300, South Africa.

Published: February 2009

The title compound, [Cu(NO(3))(C(18)H(15)P)(3)]·CH(3)OH, is a methanol solvate derivative of nitratotris(triphenyl-phos-phine)copper(I). The complex crystallizes with three triphenyl-phosphine ligands coordinated to the copper centre, with an O-H⋯O hydrogen bond observed between the nitrate ligand and the methanol solvent mol-ecule. The coordination around the Cu(I) centre is distorted tetrahedral.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968546PMC
http://dx.doi.org/10.1107/S1600536809004620DOI Listing

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