Poly[dichloridobis(μ(2)-di-4-pyridyl sulfide-κN,N')cobalt(II)].

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People's Republic of China.

Published: February 2009

In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa-hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra-molecular C-H⋯N and C-H⋯Cl hydrogen bonds.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968483PMC
http://dx.doi.org/10.1107/S1600536809001676DOI Listing

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