Poly[1-ethyl-3-methyl-imidazolium [tri-μ-chlorido-chromate(II)]].

Acta Crystallogr Sect E Struct Rep Online

Published: January 2009

The title compound, {(C(6)H(11)N(2))[CrCl(3)]}(n), was generated via mixing of the ionic liquid 1-ethyl-3-methyl-imidazolium chloride with CrCl(2) in ethanol. Crystals were obtained by a diffusion method. In the crystal structure, the anion forms one-dimensional chains of chloride-bridged Jahn-Teller distorted chromium(II) centers extending along the [100] direction. The imidazolium cations are positioned between these chains.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968286PMC
http://dx.doi.org/10.1107/S1600536809002281DOI Listing

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