Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Bijie University, Bijie 551700, People's Republic of China.

Published: January 2009

In the title compound, [Ag(C(6)H(5)NO(2))(2)]ClO(4), the Ag(I) atom shows an almost linear coordination geometry, defined by two N atoms from two pyridine-3-carboxylic acid ligands. The complex cations are linked by hydrogen bonds between the carboxyl groups into a chain. The chains are further connected through C-H⋯O hydrogen bonds and a weak Ag⋯O inter-action [2.757 (8) Å] into a layer. Another Ag⋯O inter-action [2.899 (2) Å] and a C-H⋯O hydrogen bond connect the layers into a three-dimensional network.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968163PMC
http://dx.doi.org/10.1107/S1600536808044206DOI Listing

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