AI Article Synopsis
- The compound features two Fe(II) atoms, two naphthalene-1,4-dicarboxylate anions, and two 4,4'-bipyridine ligands in its asymmetric unit.
- Each Fe(II) atom is surrounded by four oxygen atoms from the naphthalene anions and two nitrogen atoms from the bipyridine ligands, forming a distorted octahedral structure.
- The Fe(II) atoms are linked through carboxylate groups to create dimers, which form chains that are further organized into layers and interconnected into a three-dimensional network by the bipyridine ligands.
Article Abstract
The asymmetric unit of the title compound, [Fe(C(12)H(6)O(4))(C(10)H(8)N(2))], consists of two independent Fe(II) atoms, two naphthalene-1,4-dicarboxyl-ate anions and two 4,4'-bipyridine ligands. The Fe(II) atoms are each coordinated by four O atoms of the naphthalene-1,4-dicarboxyl-ate anions and two N atoms of the 4,4'-bipyridine ligands within a distorted octa-hedron. Two Fe(II) atoms are bridged via the carboxyl-ate groups of two symmetry-related anions into dimers, which are further connected into chains. These chains are linked by additional anions into layers that are finally connected by the 4,4'-bipyridine ligands into a three-dimensional coordination network.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968022 | PMC |
| http://dx.doi.org/10.1107/S1600536808042992 | DOI Listing |
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