In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8)°. One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732 (18) Å. The packing is stabilized by weak C-H⋯O inter-actions.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967862PMC
http://dx.doi.org/10.1107/S1600536808040385DOI Listing

Publication Analysis

Top Keywords

bipy ligand
8
square plane
8
22'-bipyridine2-formyl-6-methoxy-phenolatonickelii perchlorate
4
perchlorate title
4
title compound
4
compound [nic8h7o3c10h8n2]clo4
4
[nic8h7o3c10h8n2]clo4 niii
4
niii atom
4
atom distorted
4
distorted square-planar
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!