Poly[(μ(6)-naphthalene-1,4-dicarboxyl-ato-κO:O:O:O:O:O)iron(II)].

Acta Crystallogr Sect E Struct Rep Online

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24098 Kiel, Germany.

Published: December 2008

In the title compound, [Fe(C(12)H(6)O(4))](n), the Fe(II) atom is coordinated by six O atoms from six symmetrically equivalent naphthalene-1,4-dicarboxyl-ate ligands in a strongly distorted octa-hedral geometry. These octa-hedra are connected via common edges into chains that elongate along the a axis, with Fe⋯Fe distances of 2.9712 (4) and 2.9724 (4) Å. The chains are linked via the naphthalene-1,4-dicarboxyl-ate ligands into a three-dimensional coordination network.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968007PMC
http://dx.doi.org/10.1107/S1600536808042669DOI Listing

Publication Analysis

Top Keywords

naphthalene-14-dicarboxyl-ate ligands
8
poly[μ6-naphthalene-14-dicarboxyl-ato-κooooooironii] title
4
title compound
4
compound [fec12h6o4]n
4
[fec12h6o4]n feii
4
feii atom
4
atom coordinated
4
coordinated atoms
4
atoms symmetrically
4
symmetrically equivalent
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!