The structure of the title compound, (C(24)H(20)P)(2)[Te(2)I(6)], is composed of discrete PPh(4) (+) cations and centrosymmetric [Te(2)I(6)](2-) anions. The tellurium(II) atom shows a sligthly distorted square-planar TeI(4) geometry and is coordinated to two bridging and two terminal iodine atoms. The planar [Te(2)I(6)](2-) ions are isolated by the cations and no inter-molecular tellurium-halogen or halogen-halogen inter-actions are present.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959816 | PMC |
| http://dx.doi.org/10.1107/S1600536808035927 | DOI Listing |
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