The complete title complex, [Cd(2)(NO(3))(4)(C(30)H(42)N(15)P(3))], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclo-triphosphazene ligand located on the rotation axis. The non-planar cyclo-triphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyrazolyl ligands are bound to the Cd metal atoms. Each of these two symmetry-related Cd atoms is coordinated by two bidentate nitrato ligands, two exocylic pyrazolyl N atoms, and one cyclo-triphosphazene N atom.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959902 | PMC |
http://dx.doi.org/10.1107/S160053680803585X | DOI Listing |
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