The title compound, C(16)H(13)ClO(3), is an important inter-mediate in the conversion of isocoumarin to 3,4-dihydro-isocoumarin. The two aromatic rings are oriented at a dihedral angle of 67.18 (3)°. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers. There is also a C-H⋯π contact between the benzoic acid and 4-chloro-benzyl rings.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959499 | PMC |
| http://dx.doi.org/10.1107/S160053680803451X | DOI Listing |
Publication Analysis
Top Keywords
2-[4-chloro-benz-ylcarbonyl-meth-yl]benzoic acid
4
acid title
4
title compound
4
compound c16h13clo3
4
c16h13clo3 inter-mediate
4
inter-mediate conversion
4
conversion isocoumarin
4
isocoumarin 34-dihydro-isocoumarin
4
34-dihydro-isocoumarin aromatic
4
aromatic rings
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!