2,2'-{1,1'-[Pentane-1,5-diyl-bis(oxy-nitrilo)]-diethyl-idyne}diphenol.

Acta Crystallogr Sect E Struct Rep Online

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

Published: October 2008

In the title compound, C(21)H(26)N(2)O(4), there is half a mol-ecule in the asymmetric unit with a crystallographic twofold rotation axis passing through the central C atom of the -CH=N-O-(CH(2))(5)-O-N=CH- bridge. The dihedral angle formed by the two benzene rings is 80.85 (2)°. Strong intra-molecular O-H⋯N and C-H⋯O hydrogen bonds help to establish the molecular conformation. There are also weak inter-molecular π-π stacking inter-actions between neighbouring benzene rings [centroid-centroid separation = 3.502 (3) Å].

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959680PMC
http://dx.doi.org/10.1107/S160053680803136XDOI Listing

Publication Analysis

Top Keywords

benzene rings
8
22'-{11'-[pentane-15-diyl-bisoxy-nitrilo]-diethyl-idyne}diphenol title
4
title compound
4
compound c21h26n2o4
4
c21h26n2o4 half
4
half mol-ecule
4
mol-ecule asymmetric
4
asymmetric unit
4
unit crystallographic
4
crystallographic twofold
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!