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A new monoclinic polymorph of trans-dichloridodipyridine-palladium(II). | LitMetric

A new monoclinic polymorph of trans-dichloridodipyridine-palladium(II).

Acta Crystallogr Sect E Struct Rep Online

National Changhua University of Education, Department of Chemistry, Changhua 50058, Taiwan.

Published: October 2008

AI Article Synopsis

Article Abstract

In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is inter-molecular π-π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993 ▶). Acta Cryst. C49, 84-85; Liao & Lee (2006 ▶). Acta Cryst. E62, m680-m681].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959498PMC
http://dx.doi.org/10.1107/S1600536808033552DOI Listing

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