The asymmetric unit of the title compound, C(26)H(26)O(6), contains only a half-mol-ecule, the other half being generated by an inversion center. The two carboxy-phenoxy-methyl units occupy the 1,4-positions of the central aromatic ring. The central ring and the six linked C atoms are almost planar, with a maximum deviation of 0.0286 (17) Å, and the plane makes a dihedral angle of 75.50 (6)° with the benzene ring. In the crystal, strong O-H⋯O hydrogen bonds between the carboxyl groups of adjacent mol-ecules and C-H⋯π inter-actions link the mol-ecules into zigzag chains along (220) and (10); the two types of chain are arranged alternately, forming a three-dimensional framework.
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http://dx.doi.org/10.1107/S1600536810011220 | DOI Listing |
Small Methods
December 2024
School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China.
All-inorganic cesium lead halide (CsPbX, X = Cl, Br, I) perovskite quantum dots (PeQDs) are successfully incorporated within the cages of zirconium-based UiO-series metal-organic frameworks (MOFs) using in situ ship-in-a-bottle method at room temperature under ambient conditions. The resulting mBPP-MOF, which includes the 4,4'-(2,2'-bipyridyl-5,5'-diyl)dibenzoic acid (HBPP) linker, features a larger cavity size than UiO-66 and UiO-67-bpy, allowing for uniform accommodation of PeQDs within its cages. This PeQDs@MOF hybrid heterostructure enhances the separation and transfer of photogenerated charges, enabling the synthesized CsPbBr@mBPP-MOF to demonstrate highly selective and stable performance in the photocatalytic oxidation of toluene under visible light irradiation at 395 nm.
View Article and Find Full Text PDFGreen Chem
May 2024
State Key Laboratory of Environmental Criteria and Risk Assessment, National Engineering Laboratory for Lake Pollution Control and Ecological Restoration, State Environmental Protection Key Laboratory for Lake Pollution Control, Chinese Research Academy of Environmental Science, Beijing, China.
The global plasticizer market is projected to increase from $17 billion in 2022 to $22.5 billion in 2027. Various emerging/alternative plasticizers entered the market following the ban on several phthalate plasticizers because of their harmful effects.
View Article and Find Full Text PDFJ Fluoresc
May 2024
Department of Chemistry, Punjabi University, Patiala-147002, Punjab, India.
A low cost imine-decorated linker, 4,4'-(hydrazine-1,2-diylidenedimethylylidene)dibenzoic acid was utilized for the preparation of copper-based metal-organic framework (MOF) denoted as Cu-L via a solvothermal technique. The synthesized MOF material has been fully characterized by different analytical techniques such as Fourier-transform infrared (FT-IR) spectroscopy, powder X-Ray diffraction (PXRD), scanning electron microscopy (SEM), energy dispersive X-Ray spectroscopy (EDX), nitrogen adsorption-desorption isotherm analysis, and thermogravimetric analysis (TGA). It has been found that the coordination of Cu with L considerably reduced the band gap of the L of nearly about 1 eV, which is approximately 26% decline in total.
View Article and Find Full Text PDFActa Crystallogr C Struct Chem
July 2023
College of Science, Civil Aviation University of China, Tianjin 300300, People's Republic of China.
A new Pb coordination polymer, poly[0.75(aqua)[μ-4,4'-(1H,1'H-[2,2'-biimidazole]-1,1'-diyl)dibenzoato-κO,O';N;O'',O''']]lead(II)] 1.
View Article and Find Full Text PDFInorg Chem
February 2023
Department of Radiochemistry, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai201800, China.
The uranyl(VI) benzyne complex (η-CH)UOCl was prepared in the gas phase by electrospray ionization mass spectrometry coupled with collision-induced dissociation. It was formed via a dual-ligand strategy that requires the elimination of benzoic acid or benzene/CO from the uranyl dibenzoate precursor (CHCO)UOCl. This contrasts the known strategy for the formation of gas-phase benzyne complexes that would result from CO/HCl elimination from (CHCO)UOCl, during which only one benzoate ligand is involved.
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