The title Schiff base compound, C(14)H(12)BrClN(2)O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intra-molecular O-H⋯N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, mol-ecules are linked into chains along [010] via N-H⋯O hydrogen bonds. The presence of π-π inter-actions [centroid-centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983940PMC
http://dx.doi.org/10.1107/S1600536810009773DOI Listing

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