In the title compound, K(+)·C(6)H(8)NO(4) (-), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl-ene groups of the anions are always directed towards the coordinated potassium cations. The N-C-C-C torsion angle is 101.2 (2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984059PMC
http://dx.doi.org/10.1107/S1600536810010159DOI Listing

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