Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate.

Acta Crystallogr Sect E Struct Rep Online

Synthesis and Catalysis Research Centre, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, Johannesburg 2006, South Africa.

Published: March 2010

In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C-H⋯π inter-actions.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984055PMC
http://dx.doi.org/10.1107/S1600536810010032DOI Listing

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