Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au⋯O contacts = 3.054 (4) and 3.013 (4) Å, respectively, for the two mol-ecules].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983779PMC
http://dx.doi.org/10.1107/S1600536810010445DOI Listing

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