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Bis(isopropyl-triphenyl-phospho-nium) di-μ-iodido-bis-[iodidocopper(I)]. | LitMetric

Bis(isopropyl-triphenyl-phospho-nium) di-μ-iodido-bis-[iodidocopper(I)].

Acta Crystallogr Sect E Struct Rep Online

Published: March 2010

The title compound, (C(21)H(22)P)(2)[Cu(2)I(4)], prepared from reaction between copper powder, iodine and isopropyl triphenyl-phospho-nium iodide in hydroxy-acetone (acetol), shows an already known Cu(2)I(4) (2-) anion with a planar conformation [Cu-I range = 2.5108 (3)-2.5844 (3) Å and I-Cu-I range = 110.821 (10)-125.401 (10)°].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984081PMC
http://dx.doi.org/10.1107/S1600536810010196DOI Listing

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