The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C-H⋯O hydrogen-bonding inter-actions.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983736 | PMC |
| http://dx.doi.org/10.1107/S160053681000454X | DOI Listing |
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