In the title complex, [Cu(C(5)H(5)N(2)O(2))(C(14)H(18)N(3)O)(H(2)O)]·1.33H(2)O, the Cu(II) ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxy-imidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxyl-ate ligand. The apical position is occupied by a water mol-ecule. In the crystal structure, O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular network.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980135PMC
http://dx.doi.org/10.1107/S1600536809053768DOI Listing

Publication Analysis

Top Keywords

133-hydrate title
4
title complex
4
complex [cuc5h5n2o2c14h18n3oh2o]·133h2o
4
[cuc5h5n2o2c14h18n3oh2o]·133h2o cuii
4
cuii ion
4
ion coordinated
4
coordinated distorted
4
distorted square-pyramidal
4
square-pyramidal environment
4
environment basal
4

Similar Publications

Background: Intracerebral hemorrhage (ICH) causes prominent deposition of extracellular matrix molecules, particularly the chondroitin sulphate proteoglycan (CSPG) member neurocan. In tissue culture, neurocan impedes the properties of oligodendrocytes. Whether therapeutic reduction of neurocan promotes oligodendrogenesis and functional recovery in ICH is unknown.

View Article and Find Full Text PDF

Purpose: To identify the PASS and SCB thresholds for hip arthroscopy and provide guidance on how to choose among the thresholds.

Methods: A systematic review of literature was conducted in PubMed and MEDLINE databases in August 2024 using the Preferred Reporting Items for Systematic Reviews and Meta-analyses guidelines. Studies with Level I to IV evidence that defined SCB or PASS thresholds for PROs for hip arthroscopy in the setting of intra-articular pathology were included.

View Article and Find Full Text PDF

Informed consent and ethical issues pertaining to female sterilization-Scoping review.

Int J Gynaecol Obstet

January 2025

Department of Obstetrics and Gynaecology, Faculty of Health Sciences, University of Pretoria, Pretoria, South Africa.

Background: Female sterilization, a safe, permanent method of contraception that blocks the fallopian tubes, has been in use since the 19th century. The procedure necessitates informed consent, a critical step that has been marred by reports of forced sterilization since World War II. These incidents often stem from inadequate consent processes where ethical principles are overlooked or deliberately flouted.

View Article and Find Full Text PDF

Introduction: Sub-Saharan Africa is facing a severe crisis in human resources for health. Primary healthcare is the most affected. This problem is aggravated by absenteeism, implying that healthcare workers are absent on duty during scheduled working hours.

View Article and Find Full Text PDF

Hair isoniazid levels predict TB sputum culture conversion.

Int J Tuberc Lung Dis

January 2025

Department of Pharmacology and Therapeutics, Makerere College of Health Sciences, Kampala, Uganda.

BACKGROUNDSputum culture is the gold standard for diagnosing TB disease and confirming treatment outcomes. However, the turnaround time is 6-8 weeks, which leads to delays in decision-making regarding the care of TB patients.OBJECTIVETo evaluate isoniazid hair drug levels as a predictor of sputum culture conversion at 8 weeks of TB treatment.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!