In the title complex, [Ni(2)(C(13)H(11)F(2)N(6)O)(2)(C(2)H(3)O(2))(2)]·0.5CH(3)OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related Ni(II) atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each Ni(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms of the triazole groups and two bridging O atoms from two different fluconazole ligands and two O atoms from a chelating acetate ligand. In the crystal structure, the half-occupied methanol solvent mol-ecule is linked to a triazole group via an O-H⋯N hydrogen bond.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980145PMC
http://dx.doi.org/10.1107/S160053680905377XDOI Listing

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