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catena-Poly[[trimethyl-tin(IV)]-μ-(1,1'-binaphthyl-2,2'-diyl phospho-nato)]. | LitMetric

catena-Poly[[trimethyl-tin(IV)]-μ-(1,1'-binaphthyl-2,2'-diyl phospho-nato)].

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China .

Published: December 2009

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(20)H(12)O(4)P)](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the phosphate O atoms of the 1,1'-binaphthyl-2,2'-diyl phospho-nate ligands in axial positions and equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 1,1'-binaphthyl-2,2'-diyl phospho-nate ligand, forming a one-dimensional chain structure parallel to the b axis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980144PMC
http://dx.doi.org/10.1107/S160053680905291XDOI Listing

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