AI Article Synopsis
- - The compound 1-benz-yloxy-3-methyl-1-oxobutan-2-aminium chloride has a notable planar ester group with minimal deviation from its average plane and a specific angle relative to its phenyl ring.
- - Its crystal structure features chains formed by N-H⋯Cl hydrogen bonds, which connect the main components along one axis.
- - These chains are arranged in an anti-parallel fashion and further linked through additional hydrogen bonds, creating eight-membered ring structures similar to those found in other amino acid ester halides.
Article Abstract
1-benz-yloxy-3-methyl-1-oxobutan-2-aminium chloride), C(12)H(18)NO(2) (+)·Cl(-), the ester group is approximately planar, with a maximum deviation of 0.040 (2) Å from the least-squares plane, and makes a dihedral angle of 28.92 (16)° with the phenyl ring. The crystal structure is organized by N-H⋯Cl hydrogen bonds which join the two components into a chain along the b axis. Pairs of chains arranged anti-parallel are inter-connected by further N-H⋯Cl hydrogen bonds, forming eight-membered rings. Similar packing modes have been observed in a number of amino acid ester halides with a short unit-cell parameter of ca 5.5 Å along the direction in which the chains run.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979941 | PMC |
| http://dx.doi.org/10.1107/S1600536810000176 | DOI Listing |
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