In the title compound, [Zn(NCS)(C(12)H(18)N(2)O(2))(2)]NO(3), the Zn(II) ion is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands and is also coordinated by the N atom of a thio-cyanate ligand, giving a distorted trigonal-bipyramidal geometry. Intra-molecular N-H⋯O hydrogen bonds are observed in the complex cation. The nitrate anions are linked to the complex cations through N-H⋯O hydrogen bonds.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979686 | PMC |
| http://dx.doi.org/10.1107/S1600536810000036 | DOI Listing |
Publication Analysis
Top Keywords
n-h⋯o hydrogen
8
hydrogen bonds
8
bis{2-eth-oxy-6-[2-methyl-ammonioethyl-imino-meth-yl]phenolato}thio-cyanato-zincii nitrate
4
nitrate title
4
title compound
4
compound [znncsc12h18n2o22]no3
4
[znncsc12h18n2o22]no3 znii
4
znii ion
4
ion chelated
4
chelated phenolate
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!