Bis(N-phenyl-ethane-1,2-diamine)dithio-cyanato-nickel(II).

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Huzhou University, Huzhou 313000, People's Republic of China.

Published: January 2010

The asymmetric unit of the title mononuclear Ni(II) compound, [Ni(NCS)(2)(C(8)H(12)N(2))(2)], contains two independent half-mol-ecules, the Ni atoms of which lie on crystallographic inversion centres. Each Ni(II) ion is chelated by two N atoms from two N-phenyl-ethane-1,2-diamine ligands and is also coordinated by two N atoms from two thio-cyanate ligands, giving a distorted octa-hedral geometry. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (100) by N-H⋯S inter-actions.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979796PMC
http://dx.doi.org/10.1107/S1600536809055792DOI Listing

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