A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl)ethanamine-κN,P}methylpalladium(II) dichloromethane hemisolvate. | LitMetric

In the title compound, [Pd(CH(3))Cl(C(25)H(22)NPS)]·0.5C(2)H(2)Cl(2), the Pd(II) atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979533PMC
http://dx.doi.org/10.1107/S1600536810017824DOI Listing

Publication Analysis

Top Keywords

chlorido{n-[2-diphenylphosphanylbenz-ylidene]-2-2-thienylethanamine-κnp}methylpalladiumii dichloromethane
4
dichloromethane hemisolvate
4
hemisolvate title
4
title compound
4
compound [pdch3clc25h22nps]·05c2h2cl2
4
[pdch3clc25h22nps]·05c2h2cl2 pdii
4
pdii atom
4
atom coordinated
4
coordinated np-bidentate
4
np-bidentate ligand
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!