The mol-ecular structure of the title compound, C(13)H(18)N(4)O(3)S, (systematic name: ethyl N-{2-[4-(dimethyl-amino)benzo-yl]hydrazinethio-carbon-yl}carbamate) is stabilized by intra-molecular N-H⋯O=C hydrogen bonding arranged in an S(6) graph-set motif. In the crystal, inversion dimers connected via inter-molecular N-H⋯S=C hydrogen bonds [R(2) (2)(8) graph-set motif] form sheets parallel to the (21) plane. Dimers are also formed by the mol-ecules via weak inter-molecular N-H⋯S=C hydrogen bonds [R(2) (2)(10) graph-set motif] connecting the sheets.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979162PMC
http://dx.doi.org/10.1107/S1600536810015576DOI Listing

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