catena-Poly[[(5,5'-dimethyl-2,2'-bi-pyridine-κN,N')cadmium(II)]-di-μ-iodido].

Acta Crystallogr Sect E Struct Rep Online

Islamic Azad University, Shahr-e-Rey Branch, Tehran, Iran.

Published: April 2010

In the title coordination polymer, [CdI(2)(C(12)H(12)N(2))](n), the Cd(2+) ion lies on a twofold rotation axis: it is six-coordinated in a distorted cis-CdN(2)I(4) octa-hedral geometry by two N atoms from a chelating 5,5'-dimethyl-2,2'-bipyridine ligands and four bridging iodide anions. The bridging function of the iodide ions leads to a chain structure propagating in [001].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979037PMC
http://dx.doi.org/10.1107/S1600536810014091DOI Listing

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