In the title coordination polymer, [CdI(2)(C(12)H(12)N(2))](n), the Cd(2+) ion lies on a twofold rotation axis: it is six-coordinated in a distorted cis-CdN(2)I(4) octa-hedral geometry by two N atoms from a chelating 5,5'-dimethyl-2,2'-bipyridine ligands and four bridging iodide anions. The bridging function of the iodide ions leads to a chain structure propagating in [001].
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979037 | PMC |
http://dx.doi.org/10.1107/S1600536810014091 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
October 2024
Department of Chemistry, Otterbein University, Westerville, OH 43081, USA.
The title compound, -poly[[tri-aqua-sodium]-di-μ-aqua-[tri-aqua-sodium]-μ-(ethane-1,2-di-yl)bis-[(3-meth-oxy-prop-yl)phosphinodi-thiol-ato]], [Na(CHOPS)(HO)] , crystallizes in the triclinic space group 1. The dianionic [CHO(CH)P(=S)(S-)CHCHP(=S)(S-)(CH)OCH] ligand fragments are joined by a dicationic [Na(HO)] cluster that includes the oxygen of the meth-oxy-propyl unit of the ligand to form infinite chains.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
October 2024
Toyota Central R&D Labs., Inc., 41-1 Yokomichi, Nagakute, Aichi 480-1192, Japan.
The asymmetric unit of the title compound, [Co(CBrO)(CHN)(HO)] or [Co(Brbdc)(im)(HO)] , comprises half of Co ion, tetra-bromo-benzene-dicarboxylate (Brbdc), imidazole (im) and a water mol-ecule. The Co ion exhibits a six-coordinated octa-hedral geometry with two oxygen atoms of the Brbdc ligand, two oxygen atoms of the water mol-ecules, and two nitro-gen atoms of the im ligands. The carboxyl-ate group is nearly perpendicular to the benzene ring and shows monodentate coordination to the Co ion.
View Article and Find Full Text PDFIUCrdata
November 2024
Chemistry, Osnabrück University, Barabarstr. 7, 49069 Osnabrück, Germany.
In the title compound, di-phenyl-tin(IV) diiso-thio-cyanate, [Sn(NCS)(CH)] or PhSn(NCS), comparatively long tin-nitro-gen and short tin-sulfur bonds prove that the ambidentate iso-thio-cyanate ion acts as a bridge between two neighboring, octa-hedrally coordinated tin atoms. As a result, the mol-ecules lose their individuality in favor of a layered coordination polymer that represents a new type of mol-ecular inter-actions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion.
View Article and Find Full Text PDFThe title coordination polymer, [Co(N)(CHN)] , was synthesized solvothermally. The Co atom exhibits a distorted octa-hedral [CoN] coordination geometry with a bidentate 8-amino-quinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100].
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
August 2024
Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska Street 64, Kyiv, 01601, Ukraine.
The reaction of cadmium iodide with 3-amino-pyrazole (3-apz) in ethano-lic solution leads to tautomerization of the ligand and the formation of crystals of the title compound, -poly[[di-iodido-cadmium(II)]-bis-(μ-3-amino-1-pyrazole)-κ : ;κ : ], [CdI(CHN)] or [CdI(3-apz)] . Its asymmetric unit consists of a half of a Cd cation, an iodide anion and a 3-apz mol-ecule. The Cd cations are coordinated by two iodide anions and two 3-apz ligands, generating -CdNI octa-hedra, which are linked into chains by pairs of the bridging ligands.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!