La(21)Ru(9+x)In(5-x) (Pearson symbol tI140) is isotypic to the filled Y(3)Rh(2)-type structure, from which it can be derived through an ordered substitution at two sites. One of the square-prismatic sites (site symmetry ..m) is occupied by a mixture of Ru and In atoms and one of the square-antiprismatic sites (4/m..) is fully occupied by In atoms.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979065PMC
http://dx.doi.org/10.1107/S1600536810014509DOI Listing

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