AI Article Synopsis
- The compound C(16)H(26)O(5)S features an oxathiolane ring in an envelope shape, with the sulfur atom protruding slightly from the main plane of the other four atoms.
- The menthol part of the compound has a cyclohexane ring that nearly resembles an ideal chair conformation, with all substituents positioned equatorially.
- In the crystal structure, strong C-H⋯O hydrogen bonds create linear chains along the [100] direction, while additional weak interactions help pack these chains together.
Article Abstract
In the title compound, C(16)H(26)O(5)S, the oxathiol-ane ring adopts an envelope conformation, with the S atom 0.793 (3) Å out of the mean plane of the remaining four atoms. The cyclo-hexane ring of the menthol fragment adopts an almost ideal chair conformation, with all substituents in the equatorial positions. In the crystal, relatively strong, short and linear C-H⋯O hydrogen bonds link the mol-ecules into the chains along [100] direction. The chains are packed into the crystal structure by means of weak dispersive inter-actions. Inter-molecular C-H⋯S inter-actions are also observed.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971831 | PMC |
| http://dx.doi.org/10.1107/S1600536809046492 | DOI Listing |
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Article Synopsis
- The compound C(22)H(30)NO(2)P features a phosphorus atom that has an irregular tetrahedral shape.
- In the crystal structure, molecules are linked by N-H⋯O hydrogen bonds, forming chains along the b axis.
- The anilino group's phenyl ring is twisted at an angle of 77.40 (16)° compared to another phenyl ring, with the phosphorus atom having an S(p) configuration.
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