The title compound, (C(6)H(9)N(2))(2)[CuCl(4)], contains a distorted tetra-hedral [CuCl(4)](2-) anion and two protonated amino-pyridinium cations. The geometries of the protonated amino-pyridinium cations reveal amine-imine tautomerism. The crystal packing is influenced by N-H⋯Cl and C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.635 (4) and 3.642 (4)°].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971753PMC
http://dx.doi.org/10.1107/S160053680904923XDOI Listing

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