AI Article Synopsis
- - The compound [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)] features a Mo(VI) ion coordinated in an octahedral arrangement, involving various oxygen and nitrogen atoms from a Schiff base ligand and methanol.
- - The Schiff base ligand is specifically 2-meth-oxy-6-[(2-oxidoprop-yl)imino-meth-yl]phenolate, which contributes to the coordination through two deprotonated OH groups along with other atoms.
- - The crystal structure exhibits O-H⋯O hydrogen bonds that link two complexes together, creating a centrosymmetric structure that involves interactions between methanol and the ligand's oxygen atoms.
Article Abstract
In the structure of the title compound, [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)], the Mo(VI) ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth-oxy-6-[(2-oxidoprop-yl)imino-meth-yl]phenolate and by a methanol O atom. In the crystal structure, two complexes are linked via O-H⋯O hydrogen bonds, yielding a centrosymmetric arrangement involving the methanol hydr-oxy group and one of the ligand O atoms coordinated to the Mo(VI) ion.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972118 | PMC |
| http://dx.doi.org/10.1107/S1600536809047485 | DOI Listing |
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