AI Article Synopsis
- The compound described is a three-dimensional coordination polymer made of manganese (Mn), including water-coordinated and N-heterocycle-chelated Mn(II) ions in octahedral shapes.
- One of the rigid dianions connects to four Mn(II) ions through its oxygen atoms, while the other dianion binds to one Mn(II) ion with one carboxylate group and to two other Mn(II) ions with its second carboxylate group.
- This coordination setup highlights the complex bonding and structural arrangement present in the polymer.
Article Abstract
The three-dimensional coordination polymer, [Mn(2)(C(12)H(6)O(4))(2)(C(12)H(6)N(2)O(2))(H(2)O)](n), features a water-coord-inated Mn(II) ion and an N-heterocycle-chelated Mn(II) ion, both in six-coordinate octa-hedral geometries. Of the two rigid dianions, one is bonded to four Mn(II) ions, with each of the O atoms being connected to a different metal ion. The other dianion uses one carboxyl-ate group to chelate to one Mn(II) ion and its other carboxyl-ate group to bind to two Mn(II) ions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971822 | PMC |
| http://dx.doi.org/10.1107/S1600536809046388 | DOI Listing |
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