AI Article Synopsis
- The hydro-thermal reaction between SrCO(3) and 2-bromo-benzoic acid in a methanol-water mixture produced a polymeric complex, [Sr(C(7)H(4)BrO(2))(2)(H(2)O)(2)](n).
- The Sr(II) ion, which lies on a twofold symmetry axis, is coordinated by eight oxygen atoms from water molecules and carboxylate groups, creating an irregular geometry.
- The structure features chain formations connected by hydrogen bonds, resulting in a three-dimensional supra-molecular network.
Article Abstract
The hydro-thermal reaction of SrCO(3) and 2-bromo-benzoic acid in CH(3)OH-H(2)O afforded the Sr(II) title polymeric complex, [Sr(C(7)H(4)BrO(2))(2)(H(2)O)(2)](n). Within the coordination sphere, the Sr(II) ion is located on a crystallographic twofold axis, and is coordinated by eight O atoms from two water mol-ecules and four carboxyl-ate groups of 2-bromo-benzoate ligands in an irregular coordination geometry. Two μ(3)-carboxyl-ate groups of the 2-bromo-benzoate anions bridge two symmetry-related Sr(II) atoms, giving rise to a chain structure extending along [001]. The polymeric chains are connected via O-H⋯O and O-H⋯Br hydrogen bonds inter-actions into a three-dimensional supra-molecular network.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972083 | PMC |
| http://dx.doi.org/10.1107/S1600536809045395 | DOI Listing |
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