Tris(tetra-ethyl-ammonium) hydrogen bis-[2-(sulfatosulfan-yl)benzoate].

Acta Crystallogr Sect E Struct Rep Online

Published: October 2009

AI Article Synopsis

  • The reaction produces a compound with the formula 3C(8)H(20)N·H(C(6)H(4)O(5)S(2))(2) (3-), which contains a trianion made up of two linked dianions formed from 2,2'-dithio-benzoic acid.
  • The trianion is connected by an acid hydrogen atom across a center of inversion.
  • One of the cation structures is disordered, indicating a level of complexity in its arrangement around another center of inversion.

Article Abstract

The reaction between tetra-ethyl-ammonium hydroxide and 2,2'-dithio-benzoic acid yields the title compound, 3C(8)H(20)N·H(C(6)H(4)O(5)S(2))(2) (3-), the trianion of which comprises two 2-(sulfato-sulfan-yl)benzoate dianions linked across a center of inversion by an acid H atom. One of the cations is disordered about another center of inversion.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971119PMC
http://dx.doi.org/10.1107/S1600536809041415DOI Listing

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