An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S-Au-P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra-molecular Au⋯O contact [3.019 (6) Å]. In the crystal, the packing is stabilized by a network of C-H⋯S, C-H⋯N and C-H⋯O contacts.
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http://dx.doi.org/10.1107/S1600536809043876 | DOI Listing |
Acta Crystallogr Sect E Struct Rep Online
March 2010
The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P) polymorph [Hall et al. (1993 ▶). Aust.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
May 2010
The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01 (4)°]; a close intra-molecular Au⋯O contact [2.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
May 2010
Each gold atom in the binuclear title compound, [Au(2)(C(9)H(9)N(2)O(3)S)(2)(C(25)H(22)P(2))], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angles = 172.77 (6) and 173.84 (6)°], with the distortion due in part to a close intra-molecular Au⋯O contact [2.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
May 2010
The binuclear title compound, [Au(2)Fe(C(9)H(10)NOS)(2)(C(17)H(14)P)(2)]·CH(2)Cl(2), which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1:1 dichloro-methane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1-Au-P1 angle is 175.35 (5) °] which is due to an intra-molecular Au⋯O contact [3.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
October 2009
An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S-Au-P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra-molecular Au⋯O contact [3.019 (6) Å].
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