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(2-Acetyl-phenolato)(2,2'-bipyridine)nitratocopper(II). | LitMetric

(2-Acetyl-phenolato)(2,2'-bipyridine)nitratocopper(II).

Acta Crystallogr Sect E Struct Rep Online

School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, People's Republic of China.

Published: October 2009

In the title compound, [Cu(C(8)H(7)O(2))(NO(3))(C(10)H(8)N(2))], the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by two N atoms from a 2,2'-bipyridine ligand and two O atoms from the 2-acetyl-phenolate anion. The axial position is occupied by one O atom of a nitrate anion. In the bipyridine ligand, the two pyridine rings are slightly twisted by an angle of 3.5 (1)°. The crystal structure is stabilized by C-H⋯O hydrogen bonds.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971079PMC
http://dx.doi.org/10.1107/S1600536809042718DOI Listing

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